Basic chemistry of phenol formaldehyde resin: Part 2
Chemistry of Novolak resin: The word Novolak is derived from two words Novo + lack. Latin word "Novo" refers to novel or new and Swedish word "lack" refers to lacquer. The name Novolak was termed since it had replaced the natural lacquers like shellac and copal resin. Novolak resins are formed by reaction of excess moles of phenol to moles of formaldehyde in the presence of acid catalysts. Generally, the mole ratio (formaldehyde: phenol) of Novolak resins range from 0.5 to 1.0 depends on the demand from the application. Novolaks are stable at room temperature and therefore shelf life of the resin is longer and generally it's six months. But, it can last long if its stored in controlled conditions. In chemistry point of view, in the first step, addition of formaldehyde forms a methylol group in either ortho-para positions of phenol. Under normal conditions, o-p isomer has more possibility compared to p-p' and o-o' bridges. As a next step, methylol group f...